Pyroscience Pico-ph Oem Fiber-optic Ph Meter Instruction Manual (+ PDF)

Contents hide

1 Pico-pH OEM Fiber-Optic pH Meter

2 Pico-pH OEM Fiber-Optic pH Meter

2.1 Introduction

2.2 Overview

2.3 pH Sensors

2.3.1 Contactless Sensor Spots

2.3.2 Flow-through Cells

2.3.3 Documents / Resources

2.3.3.1 References

Pico-pH OEM Fiber-Optic pH Meter

Version: V1.07

Manufacturer: PyroScience GmbH

Website: www.pyroscience.com

Introduction

Option 1: For initial evaluation purposes, the Pico-pH can be
operated with the simple and customer-friendly logger software Pyro
Workbench. This software offers comfortable settings and
calibration wizards, as well as advanced logging features. It
requires an encoded USB interface cable (item no. PICO-USB) for
connecting the module to a Windows PC.

Option 2: For advanced evaluation purposes, the module can be
operated with the software Pyro Developer Tool. It offers simple
settings and calibration procedures, as well as basic logging
features. This software also requires an encoded USB interface
cable (item no. PICO-USB) for connecting the module to a Windows
PC.

Option 4: For advanced custom integration, the full USB/UART
communication protocol is available on request, allowing custom
software full control over all settings, calibration, and
measurement features of the module.

Overview

The Pico-pH is a fiber-optic pH meter. It has a front port for
connecting an optical fiber used for read-out of optical pH
sensors, as well as solder points for an external temperature
sensor enabling automatic temperature compensation. The backside of
the module provides the connector for the power supply and the
digital communication interface, as well as a red status LED.

pH Sensors

Contactless Sensor Spots

The Pico-pH can be connected to pH sensor spots via an optical
fiber or a rod.

Connection via optical fiber: Connect the pH sensor spots to
the Pico-pH using an optical fiber.
Connection via rod: Connect the pH sensor spots to the Pico-pH
using a rod.

Flow-through Cells

The pH flow-through cells (PHFLOW) can be connected to the
Pico-pH via the optical fiber PICFIB2. No additional adapter is
needed for this connection.

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Pico-pH OEM Fiber-Optic pH Meter
MANUAL
pH

Version V1.07

www.pyroscience.com

Pico-pH | Manual
Pico-pH OEM Fiber-Optic pH Meter
Document Version 1.07

The Pico-pH is released by:

PyroScience GmbH Hubertusstrasse 35 52064 Aachen Germany

Phone Fax Email Web

+49 (0)241 5183 2210 +49 (0)241 5183 2299 [email protected] www.pyroscience.com

Registered: Aachen HRB 17329, Germany

Pico-pH | Manual

TABLE OF CONTENT
1 Introduction ……………………………………………………………………………………………………………………. 5
2 Overview ………………………………………………………………………………………………………………………… 6 2.1 pH sensors…………………………………………………………………………………………………………………………6 2.1.1 Contactless sensor spots…………………………………………………………………………………….6 2.1.2 Flow-through cells……………………………………………………………………………………………….7 2.1.3 Vials ………………………………………………………………………………………………………………………..7 2.2 Connection of fibers and rods to the optical port …………………………………………………….8 2.3 External temperature sensor…………………………………………………………………………………………8 2.4 Status LED …………………………………………………………………………………………………………………………9 2.5 USB interface cable …………………………………………………………………………………………………………9
3 Option 1: Operating the Module with Pyro Workbench……………………………………………. 11 3.1 Installing the software Pyro Workbench …………………………………………………………………. 11 3.2 Using the software Pyro Workbench ……………………………………………………………………….. 12
4 Option 2: Operating the module with Pyro Developer Tool …………………………………….. 13 4.1 Installing the software Pyro Developer Tool ………………………………………………………….. 13 4.2 Using the software Pyro Developer Tool ………………………………………………………………… 14
5 Option 3: Simplified Custom Integration ……………………………………………………………………. 15 5.1 Configuring the Module using PyroScience Software …………………………………………… 15 5.2 Electrical Connector for Custom Integration …………………………………………………………… 15 5.3 Configuration of the Serial Interface…………………………………………………………………………16 5.4 Communication Protocol …………………………………………………………………………………………….. 18 5.4.1 General Definitions……………………………………………………………………………………………18 5.4.2 MEA Trigger Measurement ………………………………………………………………………….. 18 5.4.3 CPH Calibrate pH Sensor ……………………………………………………………………………… 21 5.4.4 SVS Save Configuration Permanently in Flash Memory…………………………21 5.4.5 #VERS Get Device Information …………………………………………………………………… 22 5.4.6 #IDNR Get Unique ID Number …………………………………………………………………….. 23 5.4.7 #LOGO Flash Status LED……………………………………………………………………………….23 5.4.8 #PDWN Power Down Sensor Circuits ……………………………………………………….. 23 5.4.9 #PWUP Power Up Sensor Circuits ……………………………………………………………… 23

Pico-pH | Manual
5.4.10 #STOP Enter Deep Sleep Mode …………………………………………………………………… 24 5.4.11 #RSET Reset Device……………………………………………………………………………………….24 5.4.12 #RDUM Read User Memory ………………………………………………………………………… 24 5.4.13 #WRUM Write User Memory ………………………………………………………………………. 25 5.4.14 #ERRO Response if Error Occurred…………………………………………………………….25 5.5 Available Implementations of Communication Protocol ………………………………………. 27 6 Option 4: Advanced Custom Integration ……………………………………………………………………. 28 7 Technical Drawing……………………………………………………………………………………………………….. 29 8 Specifications ………………………………………………………………………………………………………………. 30 9 Safety Guidelines…………………………………………………………………………………………………………. 32

Pico-pH | Manual

1 INTRODUCTION
The Pico-pH (item no. PICO-PH) is a fiber-optic OEM meter for read-out of optical pH sensors from PyroScience. The Pico-pH is characterized by its small size, durability and low power consumption. This OEM module is easy to integrate and is controlled with a simple serial communication protocol. To control the Pico-pH, there are several options depending on the users´ level of experience with optical sensors:

Option 1: For initial evaluation purposes, Pico-pH can be operated with the simple and customer-friendly logger software Pyro Workbench, which is typically used by end-users. This software offers comfortable settings and calibration wizards, as well as advanced logging features. Several modules can be operated in parallel within a single window. This software requires an encoded USB interface cable (item no. PICO-USB) for connecting the module to a Windows PC (see chapter 3).
Option 2: For advanced evaluation purposes, the module can be operated with the software Pyro Developer Tool. It offers simple settings and calibration procedures, as well as basic logging features. Furthermore, additional advanced settings offer full control on all features of the module. This software requires an encoded USB-interface cable (item no. PICO-USB) for connecting the module to a Windows PC (see chapter 4).
Option 3: A simplified custom integration of the module can be realized by adjusting the settings and performing sensor calibrations using the PyroScience software Pyro Workbench or Pyro Developer Tool (requires the encoded USB interface cable PICO-USB). After closing the software, the configuration is automatically saved within the internal flash memory of the module. The module can then be integrated into a specific setup, and your custom software can perform measurements using a proprietary USB/UART communication protocol (see chapter 5).
Option 4: For advanced custom integration the full USB/UART communication protocol is available on request, allowing custom software full control on all settings, calibration and measurement features of the module (see chapter 6).

Pico-pH | Manual
2 OVERVIEW
Figure 1 provides an overview of the Pico-pH. The front provides the port for connecting an optical fiber used for read-out of optical pH sensors, as well as solder points for an external temperature sensor enabling automatic temperature compensation. The backside of the module provides the connector for the power supply and the digital communication interface, as well as a red status LED.

Figure 1: Overview of Pico-pH
2.1 pH sensors
2.1.1 Contactless sensor spots
The optical pH sensor spots (PHSP5) can be mounted in a transparent vessel or placed directly in front of an optical fiber. For mounting of pH sensor spots, please refer to the corresponding “Manual pH sensors”. Sensor spots are connected to the Pico-pH via an optical fiber. To place the fiber behind the sensor spots on the outside of the transparent vessel, an adapter (SPADBAS) is necessary. The optical fiber PICFIB2 can be used for a wall thickness of 0-5 mm. Moreover, rods can be used instead of fibers when the Pico-pH is placed directly behind the sensor spot. Depending on the wall thickness of the transparent container, two different rods can be used. PICROD2 can be used for pH read out through a wall thickness of 0-5 mm and PICROD3 for a wall thickness of up to 10 mm.

Pico-pH | Manual

Figure 2: Connection of pH sensor spots to Pico-pH via an optical fiber (left) or a rod (right).
2.1.2 Flow-through cells The pH flow-through cells (PHFLOW) can be connected via the optical fiber PICFIB2 to a Pico-pH. In contrast to the sensor spots, no additional adapter is needed.

Figure 3: Connection of pH flow-through cell to Pico-pH via an optical fiber.
2.1.3 Vials pH vials (PHVIAL20) can be connected via the optical fiber PICFIB2 to a Pico-pH. To connect the optical fiber to the vial, an adapter (ADVIAL20T) is necessary.

Figure 4: Connection of a pH vial to Pico-pH via an optical fiber.

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2.2 Connection of fibers and rods to the optical port
The optical fibers or the fiber rods must be connected to the optical port of the Pico-pH with their instrument end (IE). At the IE, the core of the optical fiber protrudes ca. 1 mm from the fiber jacket. The instrument end IE is marked with “Instrument” on the attached label. For PICROD2, the AE is indicated via a black ring. For connecting an optical fiber, Pico-pH provides a clamping screw for fibers and rods. To insert the optical fiber/rod, slightly loosen the nut at the sensor port of the Pico-pH. Remove the protective cap from the optical fiber/rod and insert the IE carefully into the sensor port of the Pico-pH until there is resistance. The insertion length is about 24 mm. Fasten the nut with your fingers for fixing the fiber/rod. When using contactless sensors, insert the adapter end (AE) of the optical fibers/rods into the basic spot adapter, adapter ring or flow-through cell and fix it with the clamping screw.
2.3 External temperature sensor
The signal of pH sensors is temperature dependent, which can be automatically compensated. Pico-pH offers a high-precision sensor interface, which can be directly connected to a Pt100 temperature sensor (not included, item no. TSUB21-NC). The temperature sensor has to be soldered to the 4 solder pads at the front of the module. The temperature sensor has to be placed into the sample of the pH measurements.

Figure 5: Connecting a resistive temperature sensor to the module

The Pt100 temperature sensor has to be soldered to the 4 solder pads at the front of the module (Figure 5). For short distances (e.g. 10 cm) a simple 2-wire connection might be

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sufficient. For this, it is important to shortcut the outer with the inner solder pads as indicated in Figure 5. For longer distances and/or for high precision measurements a 4wire connection should be preferred.
In order to minimize potential electrical noise coupling into the external temperature sensor, the cables should be twisted and kept as short as possible.

2.4 Status LED
The behavior of the status LED is given in Table 1.

Table 1: Status LED

Status Power-Up Active
Deep sleep

Description

Behavior of status LED

The power supply is switched on.

A correct startup of the module is indicated by 4 flashes within 1-2 seconds.

The module is either in idle mode waiting for a new command, or it is executing a command. While the power supply is still enabled, the module can be put into deep sleep mode by the #STOP command.

The LED flashes periodically with 1s interval.
The LED is switched off.

#LOGO-command The #LOGO-command is sent to The LED flashes 4 times within

the module.

1-2 seconds.

2.5 USB interface cable
For the operation of Pico-pH with a Windows PC, a coded USB interface cable (item no. PICO-USB) is available from PyroScience. It includes a license for the comfortable logger software Pyro Workbench and the software Pyro Developer Tool. Especially for initial testing purposes this software packages can speed up OEM-developments significantly. Additionally, the USB interface cable PICO-USB provides a virtual COM-port. Custom

Pico-pH | Manual
software can use this virtual COM-port for communicating directly with the module based on the communication protocol.

Pico-pH | Manual
3 OPTION 1: OPERATING THE MODULE WITH PYRO WORKBENCH
For initial evaluation purposes the module can be operated with the simple and customer-friendly software Pyro Workbench, which is typically used by end-users. This software offers comfortable settings and calibration wizards, as well as advanced logging features. Several modules can be operated in parallel within a single window. This software requires an encoded USB interface cable PICO-USB for connecting the module to a Windows PC.

3.1 Installing the software Pyro Workbench

System requirements: PC with Windows 7/8/10 and min. 1000 MB free disk space.
Do not connect the USB-interface cable to your PC before the Pyro Workbench software has been installed. The software will automatically install the appropriate USB-drivers.
Installation steps:
· Download the Pyro Workbench from the downloads tab on www.pyroscience.com · unzip and start the installer and follow the instructions · connect the interface plug of the USB interface cable to the connector X1 of the
Pico-pH · connect the USB plug to an USB port of the PC. The status LED of the Pico-pH
should flash shortly indicating the correct startup of the module.

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· Start the Pyro Workbench software.
3.2 Using the software Pyro Workbench
Please refer to the Pyro Workbench manual for general operation instructions for the software (available on our website). Please refer to the pH Sensor manual for general information on handling and calibration of the pH sensors (available on our website).

Pico-pH | Manual
4 OPTION 2: OPERATING THE MODULE WITH PYRO DEVELOPER TOOL
For advanced evaluation purposes the module can be operated with the software Pyro Developer Tool. It offers simple settings and calibration procedures, as well as basic logging features. Furthermore, additional advanced settings offer full control on all features of the module. This software requires the encoded USB interface cable PICOUSB for connecting the module to a Windows PC.

4.1 Installing the software Pyro Developer Tool
System requirements: PC with Windows 7/8/10 and min. 1000 MB free disk space.
Do not connect the USB-interface cable to your PC before the Pyro Developer Tool has been installed. The software will install automatically the appropriate USB-drivers.
Installation steps: · Download the Pyro Developer Tool from the downloads tab on www.pyroscience.com · unzip and start the installer and follow the instructions · connect the interface plug of the USB interface cable the connector X1 of the Pico-pH

Pico-pH | Manual
· connect the USB plug to an USB port of the PC. The status LED of the Pico-pH should flash shortly indicating the correct startup of the module.
· Start the Pyro Developer Tool software.
4.2 Using the software Pyro Developer Tool
Please refer to the Pyro Developer Tool manual for general operation instructions for the software (available on our website). Please refer to the pH Sensor manual for general information on handling and calibration of the pH sensors (available on our website).

Pico-pH | Manual
5 OPTION 3: SIMPLIFIED CUSTOM INTEGRATION
A simplified custom integration of the module can be realized by adjusting the settings and performing sensor calibrations using the PyroScience software Pyro Workbench or the more advanced software Pyro Developer Tool (both requiring the encoded USB interface cable PICO-USB). After closing the software, the configuration is automatically saved within the internal flash memory of the module. The module can then be integrated into a specific setup, and your custom software can perform measurements using a proprietary USB/UART communication protocol.
5.1 Configuring the Module using PyroScience Software
Please install either the Pyro Workbench or the Pyro Developer Tool. Follow chapter 3 or chapter 4, respectively, how to operate the module with the PyroScience software. Adjust the settings and perform the required calibrations of the sensor. After the module has been configured, close the PyroScience software. The configuration is automatically saved within the internal flash memory. This means that the adjusted settings and the last sensor calibration are persistent even after a power cycle of the module. Now the module can be integrated into a customer specific setup via its UART interface (or via the USB interface cable with its virtual COM port).
5.2 Electrical Connector for Custom Integration
The electrical interface of the Pico-pH consists of the connector X1 (Figure 6). The package includes the fitting connector plug S1 (manufacturer: Phoenix Contact, type: PTSM0,5/4-P-2,5, Item no.: 1778858). Stripped cable ends can be connected to S1 without any soldering or crimping. When inserting or removing a stripped cable end (stripping length 6 mm, max. core diameter 0.5 mm²) into one of the connector holes of the connector S1, an internal spring mechanism has to be unlocked. This can be achieved by pushing relatively strongly with a small screw-driver (flat-bladed 2 mm in width) into the adjacent rectangular hole (Figure 6). The same manufacturer offers also fitting connector plugs for PCB mounting (details on request).

Pico-pH | Manual

Figure 6: Electrical connectors of Pico-pH
The pin configuration of the connector X1 is given in Table 2.

Table 2: Pin configuration of the connector X1

Pin Name

Function

Description

1 VCC 2 RXD
3 TXD 4 GND

Power
Digital input 3.0 V levels (3.3 V & 5 V tolerant) Digital output 3.0 V levels Power

Power supply min. 3.3 VDC max. 5.0 VDC Data receive line of the UART interface
Data transmission line of the UART interface Ground

5.3 Configuration of the Serial Interface
Pico-pH is operated via a serial interface, which is realized as a UART interface at 3.0 V levels (3.3 V and 5 V tolerant) consisting of a receive and a transmit line. The configuration of the UART-interface is as follows:
19200 baud, 8 data bit, 1 stop bit, no parity, no handshake Such an UART interface is very common for microcontrollers or microcontroller boards (e.g. Arduino or Raspberry Pi). The module can be directly connected to such UART interfaces without any further interface electronics.

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Note: The serial interface of this module is not an RS232 interface. However, the UART interface can be made compatible to RS232 by integrating an appropriate “level shifter electronics”.

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5.4 Communication Protocol

5.4.1 General Definitions

A command always starts with a specific command header (e.g. MEA, #VERS, #LOGO) optionally followed by several input parameters. Input parameters are given as human readable decimal numbers, separated by spaces from each other. Each command must be terminated by a carriage return. If the command could be successfully interpreted by the module, the response is sent back to the master after completion of the requested task. The first part of response consists always of a copy of the original command, optionally appended with output parameters, and again terminated by a carriage return. After a response has been received by the master, the module is immediately ready for receiving the next command. If the internal processing of the received command causes any error within the module, the response will be the error header #ERRO followed by a space and an error code (see below).

Syntax Definitions

MEA

Examples for a command header

#VERS

#LOGO

Examples for place holder for signed integer values transmitted

as human readable ASCII strings of decimal numbers. The

absolute maximum range of all values transmitted in the

communication protocol is from -2147483648 to +2147483647

(signed 32bit integer), if not otherwise indicated.

Space (ASCII code 0x20)

Carriage return (ASCII code 0x0D)

5.4.2 MEA Trigger Measurement
This command triggers a measurement and returns the results. Command: MEACS Response: MEACSR0R1…R17

Input Parameters:

Optical channel number. Set C=1.

If in doubt, then set S to 47!

This parameter defines the enabled sensor types,

given as decimal representation of the following bit field:

Bit 0 (add 1): optical channel Bit 1 (add 2): sample temperature (typ. the external Pt100sensor) Bit 2 (add 4): ambient air pressure Bit 3 (add 8): relative humidity within the module Bit 4 (add 16): reserved

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Bit 5 (add 32): case temperature (temperature within the module)
Example: S = 1 + 2 + 4 + 8 + 32 = 47 means, that the command will trigger the following measurements: optical channel (pH), sample temperature, case temperature, ambient air pressure, and relative humidity within the module housing.

Output Parameters:

Returns errors and/or warnings of the last measurement as a decimal

representation of the following bit field. The user has to distinguish between

warnings and errors. A warning indicates, that the measurement results are

in principle still valid, but their precision and/or accuracy might be

deteriorated. An error means, that the respective measurement result is not

at all valid.

Bit 0 (add 1): WARNING – automatic amplification level active

Bit 1 (add 2): WARNING – sensor signal intensity low

Bit 2 (add 4): ERROR – optical detector saturated

Bit 3 (add 8): WARNING – reference signal intensity too low

Bit 4 (add 16): ERROR – reference signal too high

Bit 5 (add 32): ERROR – failure of sample temperature sensor (e.g. Pt100)

Bit 6 (add 64): reserved

Bit 7 (add 128): WARNING high humidity (>90%RH) within the module

Bit 8 (add 256): ERROR – failure of case temperature sensor

Bit 9 (add 512): ERROR – failure of pressure sensor

Bit 10 (add 1024): ERROR – failure of humidity sensor

Example: R0 = 34 = 2 + 32 means, that there is a warning about low signal

intensity of the optical sensor, and that the external temperature sensor

(Pt100) had a failure.

If R0 = 0 then no error or warning appeared.

R1…R17

The results of the measurement given as 17 values. The most important

result values are highlighted.

Name

Unit

Description

dphi

m°

Phase shift of optical measurement (raw

data)

R2-R4 -reserved-

tempSample 0.001 °C

Sample temperature (typ. external Pt100 sensor)

tempCase

0.001 °C

Case temperature (internal T-sensor within module)

signalIntensity 0.001 mV

Signal intensity of the optical measurement

ambientLight 0.001 mV

Ambient light entering the sensor

pressure

0.001 mbar Ambient air pressure

R10

humidity

0.001 %RH

Relative humidity within the module housing

R11

resistorTemp 0.001 Ohm Resistance of the temperature sensor (raw

data)

R12- -reserved-

R13

R14

0.001

pH value measured by optical pH sensors

R15R17

-reserved-

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This command is the essential command for triggering measurements. If the input parameter S is requesting several sensor types to be measured, the optical pH measurement (“optical channel”) is always performed as the last measurement. This ensures that for enabled automatic temperature compensation the sample temperature measurement (typ. external Pt100) is done before it is then used for compensating the pH measurement.
IMPORTANT: If automatic temperature compensation is enabled for the optical sensor, it is mandatory to enable Bit1 of the input parameter S!
The output parameters pH and tempSample give the results of the pH measurement and of the temperature measurement (typ. external Pt100).
The output parameter signalIntensity is a measure of the signal quality (“signal intensity”) of the connected optical pH sensor. As a rule of thumb, typical values will be in the range of 20-500 mV. Low signal intensities (<50 mV) might lead to noisy pH measurements. A low signal intensity might be an indicator that the pH sensor is not configured optimally and/or that the pH sensor is “worn out”/depleted and has to be replaced. Please note, that the signal intensity is also dependent on the actually measured pH value. Low pH values have a high signal intensity, high pH values have a lower signal intensity.
The output parameter ambientLight is a measure how much ambient infrared light is entering the pH sensor. In principle, such ambient light is not influencing the pH measurement. However, excess ambient light might lead to a saturation of the optical detector (indicated by an enabled ERROR Bit2 in R0), which will lead to an invalid pH measurement. As a rule of thumb, the sum of signalIntensity and ambientLight should be kept below ca. 2000 mV (the optical detector saturates around 2500 mV).
Example Communication: Command MEA13 Response MEA13030120000201350870161178800123022007105000 This example command triggers the measurement of the sample temperature (typ. external Pt100) and of the optical pH sensor. The highlighted output parameters of the shown example response are interpreted as follows:
R0 = 0 No error or warning occurred; the measurement is valid! tempSample = 20.135 °C signalIntensity = 87.016 mV ambientLight = 11.788 mV pH = 7.105

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5.4.3 CPH Calibrate pH Sensor

This command is used for calibrating the pH sensor at up to 3 different calibration points. The sensor must be calibrated at 2 points and a pH offset adjustment is possible for advanced users. In contrast to electrochemical pH sensors, optical pH sensors are calibrated outside of the dynamic range where the pH indicator is either fully protonated or fully deprotonated. The first calibration point is called “low pH calibration” and is performed using a highly acidic buffer (pH 2, item no. PHCAL2). As second calibration point, “high pH calibration” is performed using a highly basic buffer (pH 10.00, item no. PHCAL10 or pH 11, item no. PHCAL11). After these two calibration points, the sensor is ready to use.

“Offset calibration point” adds an offset to the pH output. This offset has to be determined using a well-known buffer at the pH value of the pKa of the sensor (e.g. a buffer with pH 8 must be used for -PK8 sensors). It is highly advised to read the pH sensor manual for more details on the calibration (equilibration time, salinity, which buffers must not be used, etc….).

Command: CPHCNPTS Response: CPHCNPTS

Input Parameters:

Optical channel number. Set C=1

Calibration point type.

N=0: low pH calibration point

N=1: high pH calibration point

N=2: offset calibration point

pH value of calibration standard in units of 10-3 pH (e.g. 3000 means pH 3

Temperature of the calibration standard in units of 10-3 °C (e.g. 20000

means 20°C)

Salinity of the calibration standard in units of 10-3 g/L (e.g. 1000 means 1

g/L)

This command performs 16 repeated optical measurements, and uses the average for the calibration. The total duration for this procedure varies between ca. 3s and ca. 6s depending on the configuration of the module. In order to keep the calibration permanently even after a power cycle, the command SVS must be executed afterwards.
5.4.4 SVS Save Configuration Permanently in Flash Memory
This command is used for storing the current configuration in the flash memory:
Command: SVSC Response: SVSC

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Input Parameters:

Optical channel number. Set C=1

Saves the actual settings and calibration as the new default values into the internal flash memory. These default values are automatically loaded after a power cycle.
Example Communication: Command: SVS1 Response: SVS1
5.4.5 #VERS Get Device Information
This command returns general information about the device. Command: #VERS Response: #VERSDNRSBF

Output Parameters:

Device ID, identifies the specific device type. For the Pico-pH the device ID

is always 4.

Number of optical channels. For the Pico-pH this value is 1.

Firmware version, e.g. R=403 designates firmware version 4.03

Bit field about available sensor types and supported optical analytes as

follows:

Bit 0-7: Available Sensor Types Bit 0: optical channel(s)

Bit 8-15: Supported Optical Analytes Bit 8: oxygen

Bit 1: sample temperature (typ. Pt100) Bit 2: pressure

Bit 9: optical temperature Bit 10: pH

Bit 3: humidity

Bit 11: CO2

Bit 4: analog in Bit 5: case temperature Bit 6: reserved

Bit 12: reserved Bit 13: reserved Bit 14: reserved

Bit 7: reserved

Bit 15: reserved

Example: S = 1 + 2 + 4 + 8 + 32 + 1024 = 1071 means, that the device

provides an optical channel as well as sample and case temperature,

pressure, and humidity sensors, and the optical channel supports the

analytes pH.

Firmware build number starting at 1 for each firmware version (reflects

minor firmware revisions which normally do not require a software or

firmware update for the user)

Bit field about available features as follows:

Bit 0: analog out 1

Bit 5: battery

Bit 1: analog out 2

Bit 6: stand-alone logging

Bit 2: analog out 3 Bit 3: analog out 4

Bit 7: sequence commands Bit 8: user memory

Bit 4: user interface (display, buttons)

Bit 9-31: reserved

Example: F = 1 + 2 + 4 + 8 + 256 = 271 means that 4 analog outputs are

supported and the module possesses a user memory. Note, the optional

analog outputs require additional hardware (more information on request).

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Example Communication: Command: #VERS1 Response: #VERS1440310712271
5.4.6 #IDNR Get Unique ID Number
This command returns the unique identification number of the respective device. Command: #IDNR Response: #IDNRN

Output Parameters:

Unique ID number. Note, this parameter is given as an unsigned 64 bit

integer!

Returns the unique identification number of the device (does NOT correspond to the serial number of the device).

Example Communication:
Command: #IDNR Response: #IDNR2296536137892833272

5.4.7 #LOGO Flash Status LED
This command lets the status LED flash for 4 times within ca. 1 s. Command: #LOGO Response: #LOGO

This command can be used to check proper communication with the device. Or it might be helpful in setups with more than one device, in order to identify which COM port is connected to which device.
5.4.8 #PDWN Power Down Sensor Circuits
This command switches off the power supply of the sensor circuits. Command: #PDWN Response: #PDWN

This command can be used for some power saving during idle operation periods. Note, that the sensor circuits are automatically powered up again, if the module receives any command (e.g. MEA) requiring a sensor measurement. This is also the case if a broadcast measurement takes place.
5.4.9 #PWUP Power Up Sensor Circuits
This command switches on the power supply of the sensor circuits.

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Command: #PWUP Response: #PWUP
The wake-up duration is up to 250 ms.
5.4.10 #STOP Enter Deep Sleep Mode
This command puts the device into a deep sleep mode with very low power consumption
Command: #STOP Response: #STOP
During deep sleep mode the device has very low power consumption). No standard communication via USB/UART is possible. The deep sleep mode can be only exit by sending a <CR> (0x0D) to the device. The device will respond then also with a single <CR> indicating that it is ready to receive new commands. The wake-up duration can be up to 250 ms.
5.4.11 #RSET Reset Device
This command triggers a reset of the device. Command: #RSET Response: #RSET
Triggers a reset of the device, as if the device experienced a power cycle.
5.4.12 #RDUM Read User Memory
This command reads values from the user memory registers. Command: #RDUMRN Response: #RDUMRNY0…YN

Input Parameters:

Address of first register to be read from the user memory (0…63)

Total number of registers to be read (1…64)

Output Parameters: Y0…YN Content of the requested user memory registers (signed 32bit integers).
The device offers a user memory of altogether 64 signed 32bit integer numbers (range 2147483648 to 2147483647) which is located in the flash memory and is therefore retained even after power cycles. This read command returns N (N=1…64) consecutive values Y1 … YN from the user memory starting at the user memory address R (R=0…63). Note, that N+R must be <=64. The content of the user memory has no influence on the module itself. It can be used for any user specific purpose.

Pico-pH | Manual

Example Communication: Command: #RDUM124 Response: #RDUM124-40323234210710-555
This example shows a command which requests the values of 4 consecutive beginning with the user memory address 12.
5.4.13 #WRUM Write User Memory
This command writes values into the user memory registers.
Command: #WRUMRNY0…YN Response: #WRUMRNY0…YN

Input Parameters:

Address of first user memory register to be written (0…63)

Total number of registers to be written (1…64)

Y0…YN Values to be written to the user memory registers (signed 32bit integers).

This command writes N (N=1…64) values Y1 … YN consecutively starting at the user memory address R (R=0…63). Note, that N+R must be <=64. This command must be used economically, because the flash memory is designed for typ. max. 20000 flash cycles. Each time this command is executed, it will trigger a flash cycle.
Example Communication: Command: #WRUM02-16777 Response: #WRUM02-16777 This example shows a command which writes the value -16 into the memory address 0, and the value 777 into the memory address 1.
5.4.14 #ERRO Response if Error Occurred
If an error occurred, the device will give the following response:
Command: any command Response: #ERROC
This error response is mostly given, if the master did not send the command with the correct communication syntax. The output parameter C represents the general PyroScience error types as given by the following table.

Note: Warnings and errors directly related to the sensor measurements (e.g. a broken Pt100 temperature sensor, or a “worn out” optical pH senor) will not result in such an #ERRO response. Instead, such warning and errors are given in the output parameter R0 of the MEA command (see above).

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C Error Type -1 General -2 Channel -11 Memory Access
-12 Memory Lock -13 Memory Flash
-14 Memory Erase
-15 Memory Inconsistent
-21 UART Parse -22 UART Rx
-23 UART Header
-24 UART Overflow
-25 UART Baudrate -26 UART Request -27 UART Start Rx
-28 UART Range -30 I2C Transfer -40 Temp Ext -41 Periphery No
Power

Description A non-specific error occurred. The requested optical channel does not exist. Memory access violation either caused by a not existing requested register, or by an out of range address of the requested value. The requested memory is locked (system register) and a write access was requested. An error occurred while saving the registers permanently. The SVS request should be repeated to ensure a correct permanent memory. An error occurred while erasing the permanent memory region for the registers. The SVS request should be repeated. The registers in RAM are inconsistent with the permanently stored registers after processing SVS. The SVS request should be repeated. An error occurred while parsing the command string. The last command should be repeated. The command string was not received correctly (e.g. device was not ready, last request was not terminated correctly). Repeat the last command. The command header could not be interpreted correctly (must contain only characters from A-Z). Repeat the last command. The command string could not be processed fast enough to prevent an overflow of the internal receiving buffer The requested baudrate is not supported. No baudrate change took place. The command header does not match any of the supported commands. The device was waiting for incoming data; however, the next event was not triggered by receiving a command. One or more parameters of the command are out of range. There was an error transferring data on the I2C bus. The communication with the sample temperature sensor was not successful. The power supply of the device periphery (sensors, SD card) is not switched on.

Pico-pH | Manual
5.5 Available Implementations of Communication Protocol
We offer libraries for controlling Pico-pH using LabView programming language. The libraries and corresponding documentation are free for download from our website.

Pico-pH | Manual
6 OPTION 4: ADVANCED CUSTOM INTEGRATION
For advanced custom integration the full USB/UART communication protocol is available on request, allowing custom software full control on all settings, calibration and measurement features of the module.

Pico-pH | Manual
7 TECHNICAL DRAWING
The solder pads have 2.54mm pitch.

Pico-pH | Manual

8 SPECIFICATIONS

General Specifications Dimensions
Weight Power supply Connector plug Power consumption
-during operation -during deep sleep mode Start-up time -from power off -from deep sleep Interface
Max. sample rate1 Operating temperature Storage temperature Max. relative humidity

L=59 mm, Ø 17mm (without the optical port) ca. 20 g min. 3.3 VDC max. 5.0 VDC Phoenix Contact PTSM0,5/4-P-2,5
typ. 10 mA typ. <100 µA (<10 µA on request)
1-2 s ca. 200 ms UART (3.0V levels, 5V tolerant), 19200 baud, 8 data bit, 1 stop bit, no parity, no handshake ca. 10 samples/s 0 to 50 ºC -20 to 70 ºC Non-condensing conditions

pH Sensor

Refer to the separately available specifications for the connected pH sensor

Port for External Temperature Sensors

Compatible sensor types

Pt100

Measurement principle
Resolution Accuracy Range Internal Temperature Sensor Resolution

2-wire or 4-wire resistance measurement via 24bit ADC <0.02 °C <+-0.2 °C -30 to 150 °C (located on internal PCB) 0.02 °C

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Accuracy Range

+-0.3 °C -40 to 125 °C

1Note: This max. sample rate refers only to the limits of the UART communication. It does not consider the actual response time of the connected optical pH sensor or of the temperature sensor.

Pico-pH | Manual
9 SAFETY GUIDELINES
Before using the Pico-pH and its sensors, read carefully the instructions and user manuals. In case of problems or damage, disconnect the instrument and mark it to prevent any further use. Consult PyroScience for advice. There are no serviceable parts inside the device. Please note that opening the housing will void the warranty. The Pico-pH is not watertight. The Pico-pH should be kept under dry and clean conditions, avoiding moisture, dust, corrosive conditions and excessive heating of the instrument (e.g. direct sun light). Calibration and application of the sensors is on the user’s authority, as well as data acquisition, treatment and publication. The sensors and the Pico-pH are not intended for medical, aerospace or military purposes or any safety-critical applications. The sensors should be used in the laboratory by qualified personnel only, following the user instructions and the safety guidelines of the manual, as well as the appropriate laws and guidelines for safety in the laboratory. Keep the sensors and the Pico-pH out of reach of children.

Pico-pH | Manual

CONTACT
PyroScience GmbH Hubertusstraße 35 52064 Aachen Deutschland

Tel.: +49 (0)241 5183 2210 Fax: +49 (0)241 5183 2299 [email protected] www.pyroscience.com

www.pyroscience.com